Best bet is to experiment. It depends a lot of the brand of tire, and the tire width as related to the rim width. You basically want the tread to fully contact the ground with even pressure. A nice way to check is to roll through a puddle while on a freshly tarred parking lot, and check the tire pattern left on the ground by the water on the tread. It's a starting point.
Most of my Manta's had a 205/60-13 radial tires on a 7" rim, so the tire and wheel were well matched width-wise. I'd run 34 front and 30 rear to help balance the chassis and provide good steering feel.
Now on my Ascona I'd run 8" front and 9" rear wheels with 235 front/245 rear tires, but in a bias ply. If I ran anything over 26 psi they would ride on the center of the tire and wear like hell! Normally ran 24/23 on those. My racing slicks however (bias ply again), would be run at 21 front and 20 rear for track days. Due to the heat of driving at high speeds, these expanded to about 28 front and 30 rear (yes my car was set up to oversteer).
Point is, you need to take into account all the factors present. Around-town jaunts won't heat the tires like high speed highway runs.
HTH,
Bob