On a synchronous-opening 38 DGAS, the accelerator pump squirts into both barrels.
But on the progressive-opening 32/36 Webers, only the primary barrel gets a shot of fuel.
That initial squirt of fuel from the accelerator should be nearly instantaneous when you hit the throttle. If not, there’s a chance the accelerator pump linkage is bent and not in contact with the plunger. It might take some tweaking to fix it.